Course Title
Advanced Structural Chemistry
教授   河合 明雄  後学期 金曜日2時限
 単 位

関連するディプロマポリシー Related Diploma Policy
自立した良識ある市民としての判断力と実践力/Judgment and practical ability as an independent citizen of sound sense
時代の課題と社会の要請に応えた専門的知識と技能/Expert knowledge and skills to address the issues of the age and the demands of society
到達目標 Target to be Reached

By learning basic quantum chemistry for molecular energies such as rotation, vibration and electronic energies, students understand the relation between chemical properties and molecular structure including energy level structures. Students also learn various spectroscopic methods, which are important to know these structural issues. Moreover, students will be able to explain chemical reaction dynamics in the light of molecular spectroscopy and quantum chemistry.

授業内容 Course Content

To know various chemical properties of molecules, their molecular structures including energy level structures are important. This course focuses on quantum mechanical view of chemical substances such as molecular rotation, vibration, spin, electronic structures and chemical bonds as well as spectroscopic studies on these quantum states. Besides, some experimental methods, in particular, molecular spectroscopic methods are introduced to understand how these molecular and energy level structures were investigated. Some advanced spectroscopic studies on chemical reactions and single molecule observations are also presented.
授業計画 Course Planning

1.分子のエネルギー(1) 並進・回転状態の量子論
2.分子のエネルギー(2) 振動・電子状態の量子論
3.分子のエネルギー(3) 電子と核スピンの量子論
4.光吸収と発光現象  アインシュタインの光吸収発光理論、時間摂動論
5.分子構造と回転状態   マイクロ波分光
6.分子変形と振動状態   赤外分光、ラマン分光
7.化学結合と電子状態   可視・紫外分光
8.光化学(1)  励起状態の物理緩和過程
9.光化学(2)  化学反応
10.化学反応における構造変化(1)  高速時間分解分光、反応速度計測
11.化学反応における構造変化(2)  遷移状態の理論と分光
12.電子スピンの化学 磁気共鳴による反応計測
13.単一分子の構造と分光(1)    蛍光分光
14.単一分子の構造と分光(2)    超高解像度蛍光顕微分光

Students learn the subjects as follows.
Students must familiarize themselves with topics described in the required learning section before coming to class. Students are encouraged to study some exercise problems relating to each subject.

1.Molecular energy (1) Quantum states for translation and rotation motions
2.Molecular energy (2) Quantum states for vibration and electronic motions
3.Molecular energy (3)  Quantum states for electron and nuclear spins
4.Light absorption and emission  
Einstein's theory for radiation, Time dependent perturbation theory
5.Molecular structure and rotation state   Microwave spectroscopy
6.Molecular vibration   IR and Raman spectroscopies
7.Chemical bond and electronic state   UV/VIS electronic spectroscopy
8.Photochemistry (1)  Physical relaxation of the excited state
9.Photochemistry (2)  Chemical reaction of the excited state
10.Structural change in chemical reaction (1)  Time resolved spectroscopy, Reaction rate
11.Structural change in chemical reaction (2)  Transition state theory and spectroscopy
12.Electron spin in chemical reaction Magnetic resonance spectroscopy
13.Single molecule spectroscopy (1)    Fluorescence measurements
14.Single molecule spectroscopy (2)    Ultra spatial resolution spectroscopy

授業運営 Course Management
全て講義形式による。 原則として英文での資料を配布し、パワーポイントと板書で講義する。


All classes are given by lectures with powerpoint presentation along with blackboard writing.
Some notes related to the lecture will be supplied at each class.
At the beginning of each class, subjects of the previous class are reviewed briefly.
Towards the end of class, students are given exercise problems related to what is taught on that day to solve.

評価方法 Evaluation Method

Final exam (70%) and exercises at each class (30%)
Final exam is a closed book exam.

オフィスアワー Office Hour (s)

After making an appointment by email, visit room 2-237.


参考書 Book (s) for Reference
P.W.Atkins『Physical Chemistry』[Oxford University Press]